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有機合成化学協会誌
Vol. 71 (2013) No. 7 p. 728-729

記事言語:

http://doi.org/10.5059/yukigoseikyokaishi.71.728

Review de Debut

Organicboronic acids are commonly used in organic synthesis, although unstable boronic acids are known to decompose competitively in the cross coupling reaction. Recently Burke developed a novel organoboron strategy that allows for the control of cross coupling reaction by using N-methyliminodiacetic acid (MIDA) as boron-protecting group. In this review, the application of MIDA boronate for total syntheses of natural product and the novel development of sp3 hybridized boronate chemistry are described.

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