有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
Review de Debut
安定型ボロン酸エステルによる天然物合成と新展開
斉藤 竜男
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ジャーナル オープンアクセス

71 巻 (2013) 7 号 p. 728-729

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Organicboronic acids are commonly used in organic synthesis, although unstable boronic acids are known to decompose competitively in the cross coupling reaction. Recently Burke developed a novel organoboron strategy that allows for the control of cross coupling reaction by using N-methyliminodiacetic acid (MIDA) as boron-protecting group. In this review, the application of MIDA boronate for total syntheses of natural product and the novel development of sp3 hybridized boronate chemistry are described.

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© 2013 社団法人 有機合成化学協会
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