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有機合成化学協会誌
Vol. 72 (2014) No. 10 p. 1154-1155

記事言語:

http://doi.org/10.5059/yukigoseikyokaishi.72.1154

Review de Debut

Functionalizations of carbonyl compounds are absolutely essential transformations in the field of organic synthesis. Carbonyl functional moieties readily react with nucleophiles (at ipso-carbon) and electrophiles (α-carbon substitution), however, the direct β-functionalization of α,β-saturated carbonyl compounds is rare, and poses a synthetic challenge. Two novel β-activation methodologies appeared in 2013, enabled by organocatalysts.

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