有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
Review de Debut
炭化水素からの直接ニトリル合成反応
喜多 祐介
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ジャーナル オープンアクセス

72 巻 (2014) 8 号 p. 940-941

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The development of synthetic method of nitrile without metal cyanide is attracting much attention in synthetic organic chemistry because classical cyanation normally requires toxic metal cyanides and careful handling to prevent the generation of HCN gas. Recently, direct nitrogenation of hydrocarbons has been accomplished as a new approach to synthesize nitriles without metal cyanide. These approaches enable the straightforward utilization of hydrocarbons in organic synthesis. This short review focuses on the direct transformation of methyl arenes, alkynes, and alkenes by using appropriate oxidant and nitrogen sources.

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© 2014 社団法人 有機合成化学協会
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