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有機合成化学協会誌
Vol. 73 (2015) No. 1 p. 76-77

記事言語:

http://doi.org/10.5059/yukigoseikyokaishi.73.76

Review de Debut

In 2009, Buchwald group demonstrated the first catalytic nucleophilic fluorination to aryl fluorides in the presence of Pd-catalyst based on tBuBrettPhos with CsF as a fluoride source. Based on the significant report, the palladium-catalyzed nucleophilic fluorination system has been modified to improve the reactivity. Additionally, some groups reported the Cu-mediated and -catalyzed nucleophilic fluorination, wherein the reactions are considered to involve the formation of Cu(III) intermediates.

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