有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
Review de Debut
可視光不斉分子間[2+2]環化反応
山岡 庸介
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ジャーナル オープンアクセス

2015 年 73 巻 2 号 p. 181-182

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Photocycloaddition reaction is one of the most useful reactions to afford the unique structures, such as cyclobutanes, which are difficult to construct by a thermal reaction. Nevertheless, there are a few reports of the enantioselective photocyclization because of the difficulty of controlling racemic background reactions that occur by just excitation of substrates. This review focuses on two reports about the enantioselective catalytic intermolecular [2+2] photocycloaddition using visible light to afford chiral functionalized cyclobutenes and cyclobutanes.

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© 2015 社団法人 有機合成化学協会
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