有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
Review de Debut
イナミドを用いた多置換エナミドの位置および立体選択的合成
田原 淳士
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ジャーナル オープンアクセス

73 巻 (2015) 7 号 p. 749-750

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Addition of boronic acids to ynamides can be a useful method to obtain enamides, which have been considered as good prochiral precursors for the synthesis of optically active compounds bearing quaternary stereogenic centers. Although the regioselectivity for carbometalation should be required, recently, highly regio- and stereocontrolled addition reactions have been developed by using transition metal catalysts. In this review, three types of regio- and stereocontrolled synthesis of multisubstituted enamides are discussed.

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