有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
Review de Debut
(π-アレーン)クロム錯体の特性を活かした触媒反応
荒江 祥永
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ジャーナル オープンアクセス

2015 年 73 巻 8 号 p. 844-845

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Complexation of an arene to a low-valent metal carbonyl, such as Cr(CO)3, transfers electron density from the aromatic ring to the metal tricarbonyl moiety. As a result, the acidity of the aromatic ring as well as of the benzylic position is enhanced. Recently, several groups have developed catalytic reactions using a (π-arene)chromium complex, which is enhanced the reactivity of the arene by complexation.

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