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有機合成化学協会誌
Vol. 73 (2015) No. 8 p. 844-845

記事言語:

http://doi.org/10.5059/yukigoseikyokaishi.73.844

Review de Debut

Complexation of an arene to a low-valent metal carbonyl, such as Cr(CO)3, transfers electron density from the aromatic ring to the metal tricarbonyl moiety. As a result, the acidity of the aromatic ring as well as of the benzylic position is enhanced. Recently, several groups have developed catalytic reactions using a (π-arene)chromium complex, which is enhanced the reactivity of the arene by complexation.

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