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有機合成化学協会誌
Vol. 73 (2015) No. 8 p. 848-849

記事言語:

http://doi.org/10.5059/yukigoseikyokaishi.73.848

Review de Debut

Hydrometalation of alkenes with transition-metal hydrides (M-H) represents an important step in transition-metal-catalyzed transformations. Most of the reactions proceeded in anti-Markovnikov fashion to afford the corresponding adducts with high regioselectivity. On the other hand, the different types of reactions of alkenes with transition-metal hydrides, such as Co-H, Mn-H, and Fe-H, have been developed, which gave the corresponding organic radical species. Recently, a number of transformation reactions of the organic radical species catalyzed by transition-metal hydride complexes have been reported. Herein, the formation of organic radical species by the reaction of transition-metal hydrides with alkenes and their recent application to practical organic synthesis are highlighted.

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