有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
Review de Debut
遷移金属ヒドリド触媒による有機ラジカル種の発生と有機合成への利用
岩﨑 真之
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ジャーナル オープンアクセス

73 巻 (2015) 8 号 p. 848-849

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Hydrometalation of alkenes with transition-metal hydrides (M-H) represents an important step in transition-metal-catalyzed transformations. Most of the reactions proceeded in anti-Markovnikov fashion to afford the corresponding adducts with high regioselectivity. On the other hand, the different types of reactions of alkenes with transition-metal hydrides, such as Co-H, Mn-H, and Fe-H, have been developed, which gave the corresponding organic radical species. Recently, a number of transformation reactions of the organic radical species catalyzed by transition-metal hydride complexes have been reported. Herein, the formation of organic radical species by the reaction of transition-metal hydrides with alkenes and their recent application to practical organic synthesis are highlighted.

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© 2015 社団法人 有機合成化学協会
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