有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
Review de Debut
ベンジル銅中間体の脱芳香環化を鍵とするスチレンへの触媒的付加とこれに伴う異常オルト位置換反応
山元 裕太郎
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ジャーナル オープンアクセス

2016 年 74 巻 3 号 p. 268-269

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An aromatic ring is extremely stable due to its large resonance energy. Generally, benzylmetallic species react with electrophiles easily at the benzylic position. Another possible reaction site of benzylmetallic species would be their ortho-positions. However, such reactions at the ortho positions have rarely been employed, especially in a catalytic fashion. This review highlights catalytic ortho-functionalizations of styrene derivatives through dearomatization of benzylcopper intermediates which are obtained by addition of copper species to styrenic double bonds.

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© 2016 社団法人 有機合成化学協会
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