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有機合成化学協会誌
Vol. 74 (2016) No. 9 p. 913-914

記事言語:

http://doi.org/10.5059/yukigoseikyokaishi.74.913

Review de Debut

A metal carbenoid is a highly active carbon species that exhibits divergent reactivity. The control of the reactivity still remains a challenging task in carbenoid chemistry. Recently, several groups have succeeded in controlling the chemoselectivity of these reactions. This mini-review highlights substrate-controlled chemoselective arene cyclopropanation over C-H insertion reaction, and catalyst-controlled C-H functionalization of electron-rich aromatic compounds.

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