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有機合成化学協会誌
Vol. 75 (2017) No. 2 p. 153-154

記事言語:

http://doi.org/10.5059/yukigoseikyokaishi.75.153

Review de Debut

Asymmetric conjugate addition reaction to β,β-disubstituted enones is one of reliable and straightforward approaches to afford ketones carrying all-carbon substituted quaternary carbon center at the β-position. Although metal-catalyzed conjugate addition reaction of organometallic nucleophiles has been developed, less is known about organocatalyzed asymmetric conjugate addition reaction to β,β-disubstituted enones. This review focuses on recent reports about organocatalyzed nitro-Michael addition and alkyl radical addition reaction to β-substituted cyclic enones.

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