有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
Review de Debut
有機触媒による共役付加反応を鍵反応とした不斉四級炭素構築法
武田 紀彦
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ジャーナル オープンアクセス

2017 年 75 巻 2 号 p. 153-154

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Asymmetric conjugate addition reaction to β,β-disubstituted enones is one of reliable and straightforward approaches to afford ketones carrying all-carbon substituted quaternary carbon center at the β-position. Although metal-catalyzed conjugate addition reaction of organometallic nucleophiles has been developed, less is known about organocatalyzed asymmetric conjugate addition reaction to β,β-disubstituted enones. This review focuses on recent reports about organocatalyzed nitro-Michael addition and alkyl radical addition reaction to β-substituted cyclic enones.

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© 2017 社団法人 有機合成化学協会
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