有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
Review de Debut
触媒的不斉oxa-Pictet-Spengler反応
川戸 勇士
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ジャーナル オープンアクセス

2017 年 75 巻 6 号 p. 673-674

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Oxocarbenium ions are key intermediates in a wide variety of important synthetic transformations. Since they have generally high reactivities and lack of basic sites suitable for interaction with chiral Lewis acids or hydrogen-bond donors, the development of catalytic enantioselective reactions involving oxocarbenium intermediates is a great challenge for chemical synthesis. This review highlights recent progress in developing catalytic enantioselective oxa-Pictet-Spengler reaction.

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