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有機合成化学協会誌
Vol. 75 (2017) No. 6 p. 673-674

記事言語:

http://doi.org/10.5059/yukigoseikyokaishi.75.673

Review de Debut

Oxocarbenium ions are key intermediates in a wide variety of important synthetic transformations. Since they have generally high reactivities and lack of basic sites suitable for interaction with chiral Lewis acids or hydrogen-bond donors, the development of catalytic enantioselective reactions involving oxocarbenium intermediates is a great challenge for chemical synthesis. This review highlights recent progress in developing catalytic enantioselective oxa-Pictet-Spengler reaction.

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