有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
Review de Debut
“Transient directing group”が可能にする究極の直截的C(sp3)-Hアリール化反応
熊田 佳菜子
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ジャーナル オープンアクセス

2019 年 77 巻 1 号 p. 69-70

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Transition-metal catalyzed C(sp3)-H functionalization is one of the most attractive reaction because it enables straightforward and economical syntheses of organic compounds. In the past decades, C(sp3)-H functionalization approaches using directing groups have been developed, however, their stoichiometric installation and removal of directing groups limit efficiency. Recently, a “transient directing group” strategy has been emerged as the solution of this program. This review highlights recent advances in C(sp3)-H arylation using a “transient directing group”.

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