有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
Review de Debut
現在でも新知見が見出されるビニルシクロプロパン転位反応
田湯 正法
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ジャーナル オープンアクセス

2019 年 77 巻 2 号 p. 183-184

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In 1959, the rearrangement of vinylcyclopropane to cyclopentene was reported, which called as “vinylcyclopropane rearrangement” in present. Due to its harsh condition, the rearrangement has been not diligently applied to synthetic chemistry. Recently, Lewis acid-mediated reaction under very mild condition has been developed, which has a wide substrate scope to provide attractive building blocks such as spirooxindole and spiroindanone.

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