2019 年 77 巻 6 号 p. 614-615
Primary amines are naturally abundant and readily available feedstock chemicals, and a number of methods have been developed to exploit them as synthetic intermediates. However, there have been no effective methods for C(sp3)-N bond transformation of primary amines with unactivated alkyl groups. This mini-review focused on development of C-C and C-B bond forming reactions from primary alkyl amines via bench-stable Katritzky pyridinium salts available in a single step from corresponding amines.