有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
Review de Debut
アルキルアミン由来のKatritzkyピリジニウム塩を用いるC(sp3)-N結合変換反応
伊藤 元気
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ジャーナル オープンアクセス

2019 年 77 巻 6 号 p. 614-615

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Primary amines are naturally abundant and readily available feedstock chemicals, and a number of methods have been developed to exploit them as synthetic intermediates. However, there have been no effective methods for C(sp3)-N bond transformation of primary amines with unactivated alkyl groups. This mini-review focused on development of C-C and C-B bond forming reactions from primary alkyl amines via bench-stable Katritzky pyridinium salts available in a single step from corresponding amines.

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