2022 年 80 巻 6 号 p. 595-596
Dehydrogenative silylation, which produces vinyl silanes, was generally regarded as a side reaction in hydrosilylation of alkenes. However, due to a utility of vinyl silanes, transition-metal catalyzed dehydrogenative silylations have been developed. This mini-review focuses on recent developments of manganese-catalyzed selective dehydrogenative silylation of alkenes.