有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
総説および総合論文
分子間および分子内フルオロフィリック効果を活用する有機合成
松儀 真人
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2024 年 82 巻 1 号 p. 37-49

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During the last 30 years, the field of “fluorous chemistry” has witnessed intriguing advancements in organic synthesis. Fluorous molecules possess an alluring characteristic of displaying remarkably high affinity towards similar molecules, despite not mixing well with organic solvents or water. This phenomenon is commonly referred to as the “fluorophilic effect.” As we stand on the brink of the 30th anniversary of the inception of fluorous chemistry, this paper introduces our recent research accomplishments concerning the utilization of intermolecular or intramolecular fluorophilic effects in synthetic reactions.

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