Journal of Synthetic Organic Chemistry, Japan
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
Syntheses of 1, 4-Dichloro-6, 11-Dihydroxynaphthacenequinone and its Derivatives.
Shiro HOJOKuniko KOMIYA
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1959 Volume 17 Issue 9 Pages 550-552

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Abstract
1, 4-Dichloro-6, 11-dihydroxynaphthacenequinone-5, 12 was synthesized from condensation of 1, 4-dihydroxynaphthalene and 3, 6-dichlorophthalic anhydride with boric anhydride as a condensation agent.Its acetylation gave 1, 4-dichloro-6, 11-diacetoxynaphthacenequinone-5, 12;oxidation with nitric acid gave 1, 4-dichloronaphthacenediquinone-6, 11;15, 12;and treating it with aniline gave 1, 4-dianilino-6, 11-dihydroxynaphthacenequinone-5, 12.
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© The Society of Syhthetic Organic Chemistry, Japan
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