有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
クロル-S-トリアジンの反応性 (第1報)
2-クロル-4, 6-ジアリルオキシ-S-トリアジンとアニリンとの反応について
松井 弘次萩原 喜久代林 敦夫添田 美信
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1960 年 18 巻 1 号 p. 53-59

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In order to clarify the effect of X on the reactivity of active chlorine atom in chloro-S-triazine derivatives having substituent groups, the reaction between A-type chloro-S-triazine derivative, and aniline has been investigated.The result of comparison of reaction velocities indicated that the reactivity of A was decreased in the order of The effect of X was mainly due to its polar effect, this was considered to be transmitted to the reacting position of s -triazine nucleus through an oxygen atom. Accordingly, it was clarified that an electron-attractive group X had a tendency to proceed the reaction of aniline easily while the X having an electron-donating property retarded the reaction.Also, the reaction between A (X=H) and type aniline substituent has been investigated.It was found that the reactivity of aniline was decreased in the order of Thus, there was a regularity that the electron-donating group in A caused an increase in the reactivity of aniline while the electron-attractive group decreased the reactivity.

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