有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
p-ビニルフェノールから数種の新高分子化合物の合成
谷本 重夫堀川 二朗岡野 正弥小田 良平
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1968 年 26 巻 12 号 p. 1102-1106

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p-Vinylphenyl glycidyl ether (1), a new vinyl epoxy monomer, was synthesized in 11.1% yield from p-vinylphenol and epichlorohydrin. (p-Vinylphenyl)-methanesulfonate and (p-vinylphenyl)-benzenesulfonate were also synthesized, and their polymers prepared.
(1) was bulk-polymerized into a new epoxy resin (3) with intrinsic viscosity of 0.81 dl·g-1 (dioxane, 30°C). (1) and (3) appeared to be useful for casting or heat adhesion. By treatment of poly-p-vinylphenol with benzenediazonium chloride, a colored polymer containing azo groups was obtained, and with cinnamoyl chloride, a photosensitive polymer was formed.

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