有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
N-スルホメチルベンズアミド類とベンズアミド類, フタルイミド, カルバゾールおよびインドールの反応
谷本 重夫堀川 二朗小田 良平
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1969 年 27 巻 1 号 p. 59-63

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Four jointed compounds by formaldehyde [N-sulfomethylbenzamide (SMB), p-chloro-N-sulfomethylbenzamide (p-CSM), N-sulfomethyl-p-toluamide (SM-p-T) and N-sulfomethyl-p-anisamide (SM-p-A)] were synthesized, and their transjointing reactions investigated.
Methylenebis-p-toluamide (MB-p-T), 4, 4'-dichloromethylenebisbenzamide (DCM) and diindolylmethane (DIM) were obtained by the reaction between SMB and each one of p-toluamide, p-chlorobenzamide and indole.
Methylenebisbenzamide (MBB), DCM, MB-p-T, methylenebis-p-anisamide (MB-p-A), p-chloro-N-phthalimidomethylbenzamide, N-carbazolylmethyl-p-chlorobenzamide and DIM were obtained by the reaction between p-CSM and each one of benzamide, p-chlorobenzamide, p-toluamide, p-anisamide, phthalimide, carbazole, and indole.
MBB, DCM, MB-p-T, MB-p-A, N-phthalimidomethyl-p-toluamide, N-carbazolylmethyl-p-toluamide and DIM were obtained by the reaction between SM-p-T and each one of benzamide, p-chlorobenzamide, p-toluamide, p-anisamide, phthalimide, carbazole and indole.
Similarly, MBB, DCM, MB-p-T, MB-p-A, N-phthalimidomethyl-p-anisamide and DIM were obtained by the reaction between SM-p-A and each one of benzamide, p-chlorobenzamide, p-toluamide, p-anisamide, phthalimide and indole, respectively.

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