1969 年 27 巻 12 号 p. 1218-1223
Various alkoxycarbonylmethyl acrylates have been prepared by a unique method.
Monochloroacetate and sodium acrylate or sodium methacrylate have been let to react in the presence of triethylamine as the catalyst at 100110°C in 38 hrs.
The alkali-resistance of these esters is inferior to that of ethyl acrylate (EA), but the acid resistance is as good as that of EA.
In the case of copolymerization between ethoxycarbonylmethyl acrylate (M1) and styrene (M2), r1 is 0.08±0.02 and r2 is 0.68±0.03. Q1 and e1 were 0.38 and 0.91 respectively.