N-スルホメチルアニリンおよび類似化合物の交換連結反応

抄録

This paper describes the results of investigation on sodium hydroxide-catalyzed transjointing reaction of four jointed compounds by formaldehyde [N-sulfomethylan ine (SMA), p-chloro-N-sulfomethylaniline (pp-CSA), N -sulfomethyl -p -toluidine (S-p-T) and N-sulfomethyl-2-naphthamide (SMN)].
Methylenebisbenzamide (MBB), methylenebis-p-toluamide (MB-p-T), 4, 4'-dichloromethylenebisbenzamide (DCM), N-phthalimidomethylaniline and diindolylmethane (DIM) were obtained by the reaction between SMA and each one of benzamide, p-toluamide, p-chlorobenzamide, phthalimide or indole.
MBB, MB-p-T, DCM, p-chloro-N-phthalimidomethylaniline and DIM were obtained by the reaction between p-CSA and each one of benzamide, p-toluamide, pchlorobenzamide, phthalimide or indole.
MBB, MB-p-T, DCM, N-phthalimidomethyl-p-toluidine and DIM were obtained by the reaction between S-p-T and each one of benzamide, p-toluamide, p-chlorobenzamide, phthalimide or indole.
Methylenebis-2-naphthamide, MB-p-T, DCM, N-phthalimidomethyl-2-naphthamide and DIM were obtained by the reaction between SMN and each one of 2 naphthamide, p-toluamide, p-chlorobenzamide, phthalimide or indole.