ジアゼニルラジカルの化学
1978 年 36 巻 5 号 p. 387-394
詳細
1978 年 36 巻 5 号 p. 387-394
Alkyl- and aryldiazenyl radicals proposed in the investigation of azoalkanes and arylazoalkanes were reviewed with respect to the products derived from them, to the contributions to the decomposition in solution and under pressure, to the life time, and to the possibility of their out-of-cage reaction. Based on the findings from the product and CIDNP studies, the life time of phenyldiazenyl radical was estimated to be 10-5 and 10-8-10-10sec, respectively.
