Zr
Applications of Organozirconium Complexes in Organic Synthesis
1979 年 37 巻 12 号 p. 1037-1040
詳細
1979 年 37 巻 12 号 p. 1037-1040
Hydrozirconation using chlorobis (η-cyclopentadienyl) hydridozirconium (IV) is a useful procedure for functionalizing alkenes, alkynes, and 1, 3-dienes via organozirconium (IV) intermediates. These intermediates react with a variety of electrophilic reagents to give organic products in high yield. Via transmetalation the zirconium intermediates also serve as precursors of reactive organometallic compounds of metallic elements whose chemistry is well established with regard to C-C bond formation processes. Some typical experimental procedures are described.
