有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
電極酸化を用いたリン化合物の反応
中井 史郎
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ジャーナル フリー

1981 年 39 巻 2 号 p. 154-160

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Studies on the reactivities of organophosphorus compounds under anodic oxidation are described. In the anodic oxidation of triphenylphosphine and trialkyl phosphites, the attack of various nucleophiles on the anodically generated cation radical of tervalent organophosphorus compounds to give the corresponding phosphonium salts has been observed.
The following anodic reactions take place; anodic alkylamination, anodic arylation, anodic alkoxylation, anodic alkylthiolation, anodic activation, anodic phosphonylation, and anodic phosphorylation.
The possibilities of their synthetic applications are also discussed.

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