有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
低温マトリックス法の有機化学への応用
不安定化学種の捕捉から低温光化学反応へ
矢部 明
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1981 年 39 巻 9 号 p. 784-794

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Low-temperature matrix isolation technique has been developed to permit the spectroscopic study of extremely unstable species. Its usefulness in organic chemistry is shown in detecting reaction intermediates and preparing unstable molecules. A brief summary of the experimental approach and the characteristics of low-temperature photochemistry is presented. The low-temperature photochemical reactions directed toward organic synthesis are discussed by the illustrative examples which can provide high selectivity or specificity.

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