有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
マスクされた求電子性オキソエチレン等価体としての共役ニトロオレフィンの合成的利用
吉越 昭
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1982 年 40 巻 5 号 p. 427-434

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Conjugated nitroolefins were found to react with silyl enol ethers, ketene silyl acetals, and 2-monoalkyl-and 2-unsubstituted 1, 3-dicarbonyl compounds to give 1, 4-diones, γ-ketoesters, triones, and furans, respectively. 1-Nitro-1-phenylthiopropene, a new nitroolefin, was synthesized and has been developed as the reagent for 3-methylfuran synthesis. Some of these reactions have also been applied to the total synthesis of gymnomitrol, curzerenone, epicurzerenone, evodone, ligularone, and isoligularone.

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