Journal of Synthetic Organic Chemistry, Japan
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
Reactions with Trichloroacetic Acid and Its Anhydride Involving Decarboxylation of Trichloroacetate Ion
Minoru SEKIYAToshiaki MORIMOTO
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1983 Volume 41 Issue 5 Pages 395-402

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Abstract
This article describes diverse and versatile reactions of trichloroacetic acid and its anhydride involving decarboxylation of trichloroacetate ion. The reactions are characterized by the behaviors of trichloromethyl anion generated by the decarboxylation, i. e. trichloromethylation and abstraction of chlorine cation. Attention has been made, in the main, to a description of authors' works in the reactions with Schiff bases, enamines and conjugated olefins, and the reactions of α-trichloromethylated amines.
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© The Society of Syhthetic Organic Chemistry, Japan
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