1988 年 46 巻 12 号 p. 1134-1148
Recent Studies on regio- and stereoselective synthesis using transmetallation reaction of organotin compounds were reviewed.
Regioselective 1, 4-dianion formations and its rearrangements, [2, 3] -sigmatropic rearrangements of allylic lithiomethyl ether and its applications to the chiral transfer reaction of steroidal side-chain, and transmetallaion of α-alkoxystannyl compounds with retention of configuration were discussed. Some applications to the total synthesis of natural products were also described.