有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
有機スズ化合物のトランスメタル化を経由する有機合成
位置および立体選択的合成
山本 忠幸本 重男山田 和俊
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1988 年 46 巻 12 号 p. 1134-1148

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Recent Studies on regio- and stereoselective synthesis using transmetallation reaction of organotin compounds were reviewed.
Regioselective 1, 4-dianion formations and its rearrangements, [2, 3] -sigmatropic rearrangements of allylic lithiomethyl ether and its applications to the chiral transfer reaction of steroidal side-chain, and transmetallaion of α-alkoxystannyl compounds with retention of configuration were discussed. Some applications to the total synthesis of natural products were also described.

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