有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
一酸化炭素の有効利用に役立つ遷移金属ケテン錯体の化学
宮下 晃
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ジャーナル フリー

1988 年 46 巻 2 号 p. 134-144

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Transition metal ketene complexes have drawn considerable attention as models for the possible intermediates implicated in the elementary carbon-carbon coupling step in surface-catalyzed or homogeneous carbon monoxide reduction. Although ketene chemistry has been investigated for over 80 years, there have been no review articles on chemistry of transition metal ketene complexes.
Three separate aspects of transition metal ketene complexes are reviewed herein, 1) formation of ketene species on catalyst-surface, 2) the preparation and structures of transition metal ketene compexes, 3) chemical properties of transition metal ketene complexes.

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