有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
1, 3-ジオキシン-4-オン誘導体の合成とその有機合成への利用
佐藤 雅之
著者情報
ジャーナル フリー

1988 年 46 巻 6 号 p. 596-609

詳細
抄録

Several synthetic methods of 1, 3-dioxin-4-one and its derivatives are described. These dioxinones undergo cycloreversion to formyl- or acylketenes, whose inter- or intramolecular trappings provide efficient routes to a variety of heterocycles. Use of 6-unsubstituted dioxinones in de Mayo reaction provides an efficient method for simultaneous introduction of acetic acid and formyl appendages at the vicinal position of alkanes. Recent synthesis of chiral spirocyclic dioxinones as well as their use in asymmetric synthesis are also described.

著者関連情報
© 社団法人 有機合成化学協会
前の記事 次の記事
feedback
Top