有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
超効率不斉水素化触媒の開発と実用的不斉合成への応用
高橋 寿森本 俊明阿知波 一雄
著者情報
ジャーナル フリー

1990 年 48 巻 1 号 p. 29-42

詳細
抄録

Recently, we have proposed a new designing concept, “Respective Control Concept”, for developing highly efficient chiral bisphosphine ligands. On the basis of our concept, new chiral bisphosphine ligands, BCPM, MOD-BPPM, MOD-DIOP, etc. have been synthesized. Their rhodium complexes have been found to show very high catalytic activity and enantioselectivity in the asymmetric hydrogenations of prochiral carbonyl and olefinic compounds. Practical asymmetric syntheses of useful biologically active compounds have been realized by using these hydrogenations as key reactions.

著者関連情報
© 社団法人 有機合成化学協会
前の記事 次の記事
feedback
Top