有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
分子認識を用いる有機化学反応
生越 久靖
著者情報
ジャーナル フリー

1992 年 50 巻 12 号 p. 1140-1147

詳細
抄録

Concept of “Molecular Recognition” in the chemistry has originated from the biological functions such as specific catalytic behavior in enzymatic reaction, highly selective binding of a signal molecule to the receptor protein and transportation of substrate between different phases. From standpoint of the modern Host-Guest chemistry, organic reactions based on molecular recognition have received particular interest of organic chemists. Firstly molecular recognition in organic reactions involves complementary interaction between host and guest molecules through reversible non-covalent bonding at multi-binding sites. Secondly activation of substrate state requires cooperative interactions at the transition state. Some recent progress in organic reactions based on molecular recognition is briefly viewed for hydrolysis, oxidation, electron transfer and synthesis catalyzed by metal complexes.

著者関連情報
© 社団法人 有機合成化学協会
前の記事 次の記事
feedback
Top