ジルコノセン-アルケン錯体を用いた選択的反応の開発
1993 年 51 巻 12 号 p. 1145-1153
詳細
1993 年 51 巻 12 号 p. 1145-1153
This article deals with a recent development of selective reactions using zirconocene-alkene complexes in our group. The following reactions are reviewed.
(i) Preparation of zirconocene-alkene complexes. (ii) Alkene-alkene coupling reactions on zirconocene. (iii) Reactions of alkene complexes with ketones or aldehydes. (iv) Selective skeleton transformation via C-C bond activation. (v) Selective functionalization of zirconacyclopentenes. (vi) Allylation reaction of alkynes using a zirconocene complex and allylic compounds. (vii) Zirconium catalyzed C-C bond formation reactions of alkenes on zirconocenes. (viii) Zirconocene catalyzed hydrosilation reactions using zirconocene-alkene complexes. (ix) Zirconocene catalyzed C-C bond formation reactions of alkynes on zirconocenes. (x) Zirco-nocene-catalyzed allylation reactions.
