電子移動における14族元素のβ効果とその有機電解合成への応用

抄録

Group 14 metals such as silicon, germanium, and tin promote electron-transfer from a π-system and a heteroatom situated at the β position. On the basis of this effect, several electroorganic rections have been developed. Especially, the effective inter- and intra-molecular carbon-carbon bond formation reactions have been achieved by anodic oxidation of heteroatom-substituted organotin compounds.