有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
キラルπ-アリル遷移金属錯体を経由する不斉反応の立体化学
広井 邦雄
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ジャーナル フリー

1995 年 53 巻 12 号 p. 1090-1101

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Our recent works concerning asymmetric synthesis via chiral π-allyl transition metal complexes are reviewed; focussed on inter- and intramolecular asymmetric palladium-catalyzed allylations of chiral enamines, imines, and hydrazones bearing allyl esters or phosphine groups, and intramolecular asymmetric metallo-ene reactions. A novel and excellent method for asymmetric α-allylation of carbonyl compounds via their chiral enamines and imines bearing allyl esters has been developed. Readily available chiral allyl esters, (S) -proline and (S) -valine allyl ester, have been found to serve as good asymmetric allylating reagents in the palladium-catalyzed reactions of the chiral enamines and imines derived from them.

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