有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
低原子価ケイ素およびゲルマニウムを配位した遷移金属錯体の合成と性質
飛田 博実荻野 博
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1995 年 53 巻 6 号 p. 530-540

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Transition-metal complexes containing low-valent silicon and germanium ligands have attracted much attention because of their unique bonding modes as well as their possible intermediacy in various transformation reactions of organosilicon and -germanium compounds mediated by transition metals. This article describes (1) some reactions involving silylene and germylene complexes, in particular the fast intramolecular scrambling of substituents on the silicon atoms in silyl(silylene)iron complexes, and (2) the synthesis, structures, and properties of some new types of such complexes ; namely, donor-stabilized bis(silylene), (silylene)(germylene), and bis(germylene) complexes.

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