ケイ素の特性を利用する炭素環形成反応の開発
1997 年 55 巻 9 号 p. 774-784
詳細
1997 年 55 巻 9 号 p. 774-784
The development of methodologies for the construction of the odd-membered carbocycles such as five- and seven-membered ring systems has become a subject of great interest for synthetic chemists since the ring systems are found in a wide variety of natural products and theoretically interesting molecules. This review describes Brook rearrangement-mediated [3+2] and [3+4] annulation methodologies which permit highly efficient construction of five- and seven-membered carbocycles, respectively.
