有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
α-フルオロホスホン酸合成の最近の進展
横松 力渋谷 皓
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2002 年 60 巻 8 号 p. 740-751

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In recent years there has been a broadly expanding interest in the synthesis of α-fluorophos-phonates. This interest has resulted from their potential utilities as mimics for biological phos-phates in the biological processes. This review is focussed on the recent development for the effi-cient synthesis of α-fluorophosphonates. The examples cited in this review are divided in four dis-tinct types of methods : (a) fluorination of phosphonates, (b) C-C bond formation of activated fluo-romethylphosphonate, (c) phosphonylation of fluoroolefins, (d) transformations of α-fluorophos-phonates.

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