有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
サイエンススポットライト賞の受賞
高橋 幸男
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ジャーナル フリー

2003 年 61 巻 10 号 p. 1002-1008

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Our article : “Total Synthesis of Cyclomaltohexaose” describing the first total synthesis of Cyclomaltohexaose had been recognized as the most requested through CAS' information services via ChemPort during 2002.
And CAS Science Spotlight sculptures were presented to Tomoya Ogawa of RIKEN and Yukio Takahashi of Daito Chemical.
Some presentations about CAS Science Spotlight and Total Synthesis of Cyclomaltohexaose are described here. CAS Science Spotlight is one of free web service that represents most frequently requested scientific articles and interesting literatures.
We had succeeded in a regio- and stereo-controlled synthesis of Cyclomaltohexaose via intramolecular cyclization of glucohexaosyl fluoride in 21 steps, 0.02% total yield starting from maltose octaacetate.

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