有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
Recent Catalytic C-H Functionalization by Carbenoid Insertion in Non-Conventional Media
蔡貞 廈
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ジャーナル フリー

2008 年 66 巻 12 号 p. 1223-1224

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? The catalytic decomposition of diazo compounds and the subsequent insertion of a carbene group into the C-H bond constitute one of the very few examples of effective catalytic functionalization of hydrocarbons. This transformation has been achieved with rhodium-, copper-, silver- and gold-based catalysts under mild conditions. Recently, the catalytic carbenoid insertion in non-conventional media has attracted attention, because such reactions offer more environmental-ly friendly organic synthetic methodologies. In this review, recent reports on this topic will be summarized.

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© The Society of Syhthetic Organic Chemistry, Japan
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