有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
パラジウムの分子内転位
安井 義純
著者情報
ジャーナル フリー

2008 年 66 巻 3 号 p. 251-252

詳細
抄録

Specific conversion of C-X bond to C-C bond by palladium-catalyzed reaction has been widely used in organic synthesis. Recently, several groups reported unusual C-C bond formation occurred at a different carbon from which halogen was initially attached. These reaction has been considered to happen through intramolecular migration of palladium before the C-C bond was formed. Larock et al. discovered a set of reaction conditions which enables to switch such migration on or off. Sharp et al. reported stepwise migration of isolated complexes. By focusing on these results, intramolecular palladium migration will be briefly discussed.

著者関連情報
© 社団法人 有機合成化学協会
前の記事 次の記事
feedback
Top