J-STAGE トップ  >  資料トップ  > 書誌事項

有機合成化学協会誌
Vol. 66 (2008) No. 9 P 906-907

記事言語:

http://doi.org/10.5059/yukigoseikyokaishi.66.906


In this short review, a new methodology of preparation of the silacyclic compounds using silylene and their application for organic synthesis are described. Silylene transfer from silacyclopropane to alkene, alkyne, imine, and α, β-unsaturated carbonyl compounds was catalyzed by silver salt to give the corresponding [1+2] or [1+4] cycloadducts in good yields. Combination of the cycloaddition, Ireland-Claisen rearrangement, and oxidative cleavage of silicon-carbon bond provided the regio-and stereoselective synthesis of polyol and α-hydroxyacid in a mild condition.

Copyright © 社団法人 有機合成化学協会

記事ツール

この記事を共有