Bulletin of the Agricultural Chemical Society of Japan
Online ISSN : 1881-1272
Print ISSN : 0375-8397
ISSN-L : 0375-8397
Volume 11, Issue 11
Displaying 1-3 of 3 articles from this issue
  • On the Chemical Constituents of “Sotetsu” pollen. I
    Kotaro NISHIDA
    1935 Volume 11 Issue 11 Pages 143-148
    Published: 1935
    Released on J-STAGE: February 07, 2011
    JOURNAL FREE ACCESS
    The principal results are summarized as follows:
    (1) General constituent of sotetsu pollen was determined; in the result it did not contained a starch.
    (2) In sotetsu pollen, the formaldehyde-containing substance was not contained.
    (3) The adenine and choline, in free state, were isolated from sotetsu pollen.
    (4) An attempt at the isolations of spermine and protamine from sotetsu pollen was ended in negative results.
    The writer wishes to express his thanks to Dr. K. Yoshimura and Prof. Dr. Y. Okuda for their having interest on the problem, and also begs to acknowledge with thanks that a part of the expense of this study was defrayed from a grant given by the Nippon Gakuzyutsu-shinkokwai.
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  • Sadayuki HAMANO
    1935 Volume 11 Issue 11 Pages 148-153
    Published: 1935
    Released on J-STAGE: February 07, 2011
    JOURNAL FREE ACCESS
    In a previous paper(1) K. Kawakami and the present author(2) have reported that they have prepared crystalline compounds of fatty acid or benzoic esters of vitamin A by condensing them with maleic anhydride, but these crystals had no physiological activity and could not be regenerated into vitamin A.
    The present author has now succeeded in preparing a crystalline ester of vitamin A by treating vitamin A concentrate (Biosterin) with β-naphthoyl chloride in presence of pyridine and proved to have the activity of 7200 C. L. O. units after Carr-Price test. It readily promotes the growth of albino rats and cures, the; xerophthalmia. Dr. S. Kato in our institute has observed that a 1/140, 000 mol methyl alcoholic solution of the crystals show absorption bands at 3595, 3385, 3060, 2920, 2816 Å besides the maximum at 3225 Å.
    The crystals have the formula C31H36O2, mp 76°, it is easily hydrolysed by alcoholic potash into β-naphthoic acid, C11H8O2, and pure vitamin A, the analysis of which agrees with the formula proposed by P. Karrer, i. e., C20H30O. Thus it has been definitely proved that the crystals are the ester of β-naphthoic acid and vitamin A.
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  • 1935 Volume 11 Issue 11 Pages 154-158
    Published: 1935
    Released on J-STAGE: February 07, 2011
    JOURNAL FREE ACCESS
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