The Tanmai pyrophyllite deposit, Quang Ninh Province, was studied geologically and mineralogically. The deposit consisting of five pyrophyllite bodies, is classified into five alteration zones: kaolin, pyrophyllite, siliceous, diaspore and alunite. All of them are characterized by low iron content. The original rocks are volcanics of rhyodacitic composition such as tuff, volcanic breccia, lava and sheeted intrusive rocks. Siliceous zone originated from felsic intrusive rocks and massive lava. The sequence of the alteration is estimated as follows: kaolin zone formed earlier under lower temperature, and pyrophyllite-and siliceous-zones followed at higher temperature. The contrast in the permeability of the original volcanics resulted in the difference of mineral composition; a pyrophyllite zone from high permeability and a siliceous zone for low permeability units. The diaspore zone has formed as fissure-flling veins selectively in the siliceous zone. This sequence of the formation probably progresses with temperature. Vein-filling diaspore + pyrophyllite in the siliceous zone has precipitated in a hydrothermal solution under decreasing P H
2O caused by vertical fissure systems. The brittle nature of the siliceous zone has developed a vein-filling diaspore. The pyrophyllite zone being the majority of the Tanmai deposit has formed at a temperature of 260-290°C, estimated by the experimental data. Finally, alunite precipitated in the declining stage of hydrothermal activity.
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