分光研究
Online ISSN : 1884-6785
Print ISSN : 0038-7002
ISSN-L : 0038-7002
3 巻, 9 号
選択された号の論文の8件中1~8を表示しています
  • 太秦 康光, 西村 雅古
    1954 年 3 巻 9 号 p. 3-10
    発行日: 1954年
    公開日: 2010/06/28
    ジャーナル フリー
  • 瀬谷 正男
    1954 年 3 巻 9 号 p. 11-14
    発行日: 1954年
    公開日: 2010/06/28
    ジャーナル フリー
  • I: 考察
    飯島 弘
    1954 年 3 巻 9 号 p. 15-20
    発行日: 1954年
    公開日: 2010/06/28
    ジャーナル フリー
    In quantitative spectrographic analysis, the normal density, D=log (opacity) as measured quantity, has been most widely used, but recently so-called Seidel-density, W=log (opacity-1), or so-called P-density, P= (D+W) /2 has often been used. But it has not been evidently confirmed that in which case the density W or P should be used, and in which points W or P is more favourable than the normal density. The author has made a theoretical study on the working-curve of the internal-standard method and compared the working-curve in Seidelscale with that in the normal-scale from the point of view of the errors.
    The results of this study are summarized as follows:
    1. The slope of working curve in Seidel-scale is steeper than that in normal scale.
    2. In practical concentration range, errors are sufficiently eliminated in the internal standard method, using the normal scale, but in this range it does not necessarily follow that the errors is sufficiently eliminated in Seidel-scale.
    3. In low concentration range sometimes Seidel-scale is more favourable but sometimes is not. Generally speaking, Seidel-scale is more favourable in case of the slope of working curve in this scale, being extremely steeper than that in normal scale.
  • II: 実験Seidel黒度による鉄鋼中の微量元素の定量分光分析
    飯島 弘
    1954 年 3 巻 9 号 p. 21-25
    発行日: 1954年
    公開日: 2010/06/28
    ジャーナル フリー
    In order to examine the results of the theoretical study in the first report, the author, applying Seidel-scale, has made an experimental study on the quantitative spectrographic analysis of elements in steels at low concentration. The results of this study are summarized as follows.
    1. In low concentration range sometimes calibration by Seidel-scale is more favourable but sometimes is not. Calibration by Seidel-scale is more favourable when the slope of the working curve in this scale is extremely steeper than in normal scale.
    2. It has been experimentally confirmed that the results of theoretical study is right.
    3. In the analysis of low concentration, the application of high energy source is rather preferable than the application of Seidel-scale.
  • 大塚 繁
    1954 年 3 巻 9 号 p. 26-31
    発行日: 1954年
    公開日: 2010/06/28
    ジャーナル フリー
    中型分光写真器使用に依り受信用真空管陽極として用いられるニッケル鍍金鉄板の鍍金量の測定法を検討した.試料は溶液となし炭素棒に浸透せしめて電極とする方法を用いた.実験結果より試料溶液作製時の溶媒濃度, 溶液濃度, 溶液の浸透時間及び撮影条件を適当に選ぶ事に依り迅速に高精度の鍍金厚さの測定が成し得られた.又本方法を適用する事に依りニッケル鍍金鉄板上の鍍金層の厚薄に就いての興味ある分布を容易に知る事が出来た.
  • (I) 検流計を用いたWadsworth Littrow型赤外分光器の試作
    工藤 恵栄
    1954 年 3 巻 9 号 p. 32-35
    発行日: 1954年
    公開日: 2010/06/28
    ジャーナル フリー
    A Wadsworth Littrow type infrared spectrometer using a galvanometer has been built. Prism is a sodium chloride of surace area IIX 8cm and angle 65°. Detector is the thermo-couple which has a long time constant and sensitivity of 3 μV/μW at 760 mmHg.
    Wave length of recording spectrum is linear, and slit is automatically opened by a slit cam. As the sensitivity of a galvanometer is 5×10-8 volt, slit must be considerably wide, so the resolution of the spectrometer is not good, nevertheless the 10μ band of ammonia was detected distinctly.
  • (II) 検流計を用いたLittrow型赤外分光器の試作
    工藤 恵栄
    1954 年 3 巻 9 号 p. 36-41
    発行日: 1954年
    公開日: 2010/06/28
    ジャーナル フリー
    In previous year, a Wadsworth Littrow type infrared spectrometer using a galvanometer was built, In the spectrometer, a prism was set at minimum deviation, the prism and Wads-worth mirror were rotated simultaneously. In this time, a Littrow type spectrometer which is not a minimum deviation type has been built, and its resolution power has been examined theoretically and experimentally.
  • 1954 年 3 巻 9 号 p. 48
    発行日: 1954年
    公開日: 2011/02/23
    ジャーナル フリー
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