Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Volume 37 , Issue 2
Showing 1-41 articles out of 41 articles from the selected issue
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  • Vladimir Ya. Lee, Masaaki Nakamoto, Akira Sekiguchi
    2008 Volume 37 Issue 2 Pages 128-133
    Published: February 05, 2008
    Released: December 22, 2007
    JOURNALS RESTRICTED ACCESS
    Recent developments in the field of stable free radicals centered on the heavy elements of groups 14 and 13, neutral and charged, are covered in this review. The diagnostic geometrical characteristics and bonding features of the title species are presented. The thermodynamic and kinetic factors, affecting the stability and electronic configuration of radicals, are also discussed, with particular emphasis being given to the stabilizing influence of the bulky silyl substituents.
    Recent developments in the field of the stable free radicals centered on the heavy elements of groups 14 and 13, both neutral and charged, are covered in the present review with a particular focus on the thermodynamic and kinetic stabilization of radical species with the bulky electropositive silyl substituents. Fullsize Image
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