Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Volume 39 , Issue 4
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  • Vladimir Ya. Lee, Akira Sekiguchi, Jean Escudié, Henri Ranaivon ...
    2010 Volume 39 Issue 4 Pages 312-318
    Published: April 05, 2010
    Released: March 13, 2010
    JOURNALS RESTRICTED ACCESS
    A number of compounds with heteronuclear double bonds between heavy elements of groups 13, 14, 15, and 16 have been isolated and characterized in the last three decades; they are kinetically stabilized by the use of bulky substituents or thermodynamically stabilized by intra- or intermolecular coordination. They are fascinating compounds in respect of their unusual chemical properties, being very useful building blocks in organometallic chemistry.
    Recent developments in the field of the heteronuclear double bonds >E=E′ (E = heavy group 14 element, E′ = group 13–16 element) are covered in the present review with a particular focus on the kinetic stabilization with the bulky substituents. Fullsize Image
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