Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Volume 40 , Issue 9
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  • Akira Suzuki, Yasunori Yamamoto
    2011 Volume 40 Issue 9 Pages 894-901
    Published: September 05, 2011
    Released: September 05, 2011
    JOURNALS OPEN ACCESS
    The palladium-catalyzed cross-coupling reaction between different types of organoboron compounds and various organic halides or triflates in the presence of base provides a powerful and general methodology for the formation of carbon–carbon bonds. The Csp2–B compounds (such as aryl- and 1-alkenylboron derivatives) and Csp3–B compounds (alkylboron compounds) readily cross-couple with organic electrophiles to give coupled products selectively in high yields. Recently, the Csp–B compounds (1-alkynylboron derivatives) have been also observed to react with organic electrophiles to produce expected cross-coupled products. The overview of some of such coupling reactions is discussed here in this article.
    The Csp2–B compounds and Csp3–B compounds readily cross-couple with organic electrophiles to give coupled products selectively in high yields. Recently, the Csp–B compounds have been also observed to react with organic electrophiles to produce expected cross-coupled products. The overview of some of such coupling reactions is discussed here in this article. Fullsize Image
Paper in Celebration for the 2010 Nobel Prize in Chemistry
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